What You Need to Know
During bulk fermentation, the sourdough starter ferments sugars via anaerobic glycolysis, producing CO₂, ethanol, and organic acids that leaven the dough and develop flavor. The alkaline boiling step gelatinizes surface starches and raises the pH, accelerating Maillard reactions during baking, which form melanoidins responsible for the characteristic crust color and aroma.
The Science
Primary Reaction
Anaerobic fermentation and Maillard browning